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Beilstein J. Org. Chem. 2013, 9, 1907–1916, doi:10.3762/bjoc.9.225
Graphical Abstract
Scheme 1: Generation of NO3• (a) in the atmosphere, (b) under experimental conditions.
Figure 1: Polyester-model systems studied in this work.
Scheme 2: Products of the reaction of polyester model compounds 1–3 with NO3• in the absence of other radical...
Scheme 3: Proposed mechanism for the reaction of m-toluic acid neopentyl ester (3) with NO3• in the absence o...
Scheme 4: Products of the reaction of polyester-model compounds 1–3 with NO3• in presence of NO2•, O3, and O2....
Scheme 5: Proposed mechanism for the reaction of m-toluic acid neopentyl ester (3) with NO3• in presence of NO...